Lecture within WDS IPAS
09:30, 23-02-21
Aula INTiBS PAN
Themal properties of crystals and amorphous solids. part 1 of 3
prof. Oleksandr Kryvchikov
INTiBS PAN
Wykład jest otwarty. The lecture is open.
Outline:
1. General information about properties of molecular matter with different structures.
- Some important experimental facts and physical ideas for the thermo physics of molecular solids.
- The concept of heat capacity. Dulong–Petit law. Experimental facts for simple and complex crystals, amorphous solids and disordered crystals.
2. Heat capacity of simple crystals.
- Crystals with complex structure. Optical phonons. Einstein's model. The law of dispersion. Heat capacity. Experimental data for simple molecular crystals.
- Heat capacity of amorphous solids and glassy-crystals. Low temperature anomalies. The boson maximum. The theoretical description. Comparative analysis between crystalline and amorphous solids. Low and ultra low thermal conductivity complex crystals.
3. Thermal conductivity of simple crystals
- Thermal conductivity of molecular crystals. Phonon-phonon scattering processes. Eucken law. Complex molecular crystals. Thermoelectric materials and other functional materials.
- Description of thermal conductivity in terms of quantum mechanics. Contribution of quasi-particles and quasi-waves to thermal conductivity. The effect of tunneling.
4. Thermal conductivity of complex crystals and amorphous solids.
- Thermal conductivity of amorphous solids and its universal behavior. The influence of pressure, irradiation, porosity, etc. Glass-like behavior of the thermal conductivity of crystals of various types. Glassy crystals.
- Theoretical description of the thermal conductivity of amorphous substances. A model of two level states. The model of soft potentials. Alain-Feldman model. Minimum thermal conductivity.
5. Thermal expansion of the molecular solids and nanostructures.